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Creators/Authors contains: "Moskovitz, Dylan A"

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  1. ; ; ; ; ; ; ; ; ; ; et al (, European Journal of Organic Chemistry)
    Abstract Herein we report the MoO2Dipic promoted sulfonation of alkenes using N−Ts‐hydroxylamine as the quantitative source of Ts. The reaction works with high yields and stereoselectivities for styrenes with a wide variety of substitution patterns. A novel atom transfer radical addition mechanism involving the formation of molybdooxaziridine complex1as the active catalyst, difunctionalization withTs‐NO, followed by oxidation, and then elimination as the rate‐determining‐step for the formation of vinylsulfone3has been proposed. Initial kinetic and mechanistic data indicates the formation ofTs‐NOand provides evidence for the proposed mechanism. 
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    Free, publicly-accessible full text available March 17, 2026
  2. ; ; ; ; ; ; ; ; ; ; et al (, Organic & Biomolecular Chemistry)
    Novel tungstenooxaziridine complex promotes the oxyamination of substituted alkenes with high stereoselectivity and stereospecificity. Mechanistic studies provide evidence for a highly selectivesyn-difunctionalization pathway. 
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    Full Text Available 
  3. ; ; ; ; ; ; ; ; ; ; et al (, The Journal of Organic Chemistry)